Organometallic chemistry
نویسندگان
چکیده
This Thematic Series is dedicated to the memory of Professor Peter Hofmann (Figure 1) whose research work included many seminal contributions to the field of organometallic chemistry [1-3]. Organometallic chemistry has therefore been chosen as the topic of this Thematic Series of the Beilstein Journal of Organic Chemistry. Over a period of many decades, the chemistry of metal–carbon bonds has given rise to an ever-growing field of fundamental research and applied science, merging the reactivity of inorganic complexes with the structural diversity of organic compounds. The contributions in this Thematic Series reflect the broad impact of organometallic compounds in various fields of modern chemical research. These include the tailoring of new ancillary ligands, the investigation of more active and more selective homogeneous catalysts, catalytic transformations in the total synthesis of natural products, the theoretical and kinetic unravelling of reaction mechanisms, and the verification of rare coordination modes. These various facets underline the importance of organometallic chemistry in its own right, but also demonstrate the vital role that research in organometallic chemistry plays as a provider of invaluable tools for other chemistry sub-disciplines.
منابع مشابه
Hybrid Organometallic-Inorganic Nanomaterial: Acetyl Ferrocene Schiff base Immobilized on Silica Coated Magnetite Nanoparticles
In this work, a new hybrid organometallic-inorganic hybrid nanomaterial was prepared by immobilization of acetyl ferrocene on the surface of magnetite nanoparticles. Covalent grafting of silica coated magnetite nanoparticles (SCMNPs) with 3-aminopropyl triethoxysilane gave aminopropyl-modified magnetite nanoparticles (AmpSCMNPs). Then, Schiff base condensation of AmpSCMNPs with acet...
متن کاملSnail shell as a natural and highly efficient catalyst for the synthesis of imidazole derivatives
A convenient, simple and green process for the synthesis of 2,4,5-triaryl-1H-imidazole and 1,2,4,5-tetraaryl-1H-imidazole derivatives using snail shell, which is abundant in Morocco, as a catalyst in ethanol at 40 °C has been developed. Additionally, short reaction times, excellent yields, simple procedure and relative non-toxicity of the catalyst are other noteworthy advantages and make this m...
متن کاملSnail shell as a natural and highly efficient catalyst for the synthesis of imidazole derivatives
A convenient, simple and green process for the synthesis of 2,4,5-triaryl-1H-imidazole and 1,2,4,5-tetraaryl-1H-imidazole derivatives using snail shell, which is abundant in Morocco, as a catalyst in ethanol at 40 °C has been developed. Additionally, short reaction times, excellent yields, simple procedure and relative non-toxicity of the catalyst are other noteworthy advantages and make this m...
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Until recently, organometallic derivatives were generally viewed as moisture- and air-sensitive compounds, and consequently very challenging to synthesise and very demanding in terms of laboratory requirements (Schlenk techniques, dried solvent, glove box). However, an increasing number of stable, water-soluble organometallic compounds are now available, and organometallic chemistry in aqueous ...
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Recently, solid-phase synthesis has been recognized as an important methodology for combinatorial chemistry or automated synthesis directed at drug discovery. Various synthetic methodologies have been applied to solid-phase synthesis, although it appears that organometallic chemistry in this area is still being explored. In solution-phase chemistry, organometallic reagents have been utilized fo...
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